Send us Fan Mail Last episode we talked about pH, and I said buffering would come back properly. Today is that episode. Cation exchange capacity (CEC) is the reason some paddocks hold onto calcium, magnesium, potassium and ammonium, and others leak them with the next decent rain. It is also a big part of why two paddocks with similar fertiliser bills can perform so differently. In this episode of Agriculture From the Ground Up we cover: what CEC actually is, using a simple car-park picture for exchange sitesthe base cations, plus ammonium, hydrogen, aluminium and manganesewhy “CEC by bases” and effective CEC (ECEC) are not the same numberhow labs measure it, and why gravelly country can look better on paper than it is in the paddockwhat the units mean and why WA sands sit so lowwhy organic matter can supply up to 85 per cent of CEC on sandy topsoilsthe awkward loop: low CEC makes it harder to keep the carbon you are trying to addhow CEC changes down a duplex profilethe pH link: low CEC means poor buffering and faster acidificationwhy nitrate leaching also drags base cations with itthe myth of the perfect calcium-to-magnesium ratiowhat to actually do with a CEC result on farmWe flag threads we will pick up later in the series (nitrogen, soil organic carbon, clay, and water holding) rather than trying to finish those stories today. Thanks to Williams Woolshed in Williams and Naked Bean Coffee Roasters in Albany. Reference list Brown, K., & Lemon, J. (n.d.). Cations and cation exchange capacity. soilquality.org.au. https://www.soilquality.org.au/factsheets/cation-exchange-capacity Cornell University Cooperative Extension. (2007). Cation exchange capacity (CEC) (Agronomy Fact Sheet Series No. 22). Department of Crop and Soil Sciences, College of Agriculture and Life Sciences, Cornell University. Grace, P. R., Ladd, J. N., Robertson, G. P., & Gage, S. H. (2006). SOCRATES — A simple model for predicting long-term changes in soil organic carbon in terrestrial ecosystems. Soil Biology and Biochemistry, 38(5), 1172–1176. Hazelton, P. A., & Murphy, B. W. (2007). Interpreting soil test results: What do all the numbers mean? CSIRO Publishing. Helling, C. S., Chesters, G., & Corey, R. B. (1964). Contribution of organic matter and clay to soil cation-exchange capacity as affected by the pH of the saturating solution. Soil Science Society of America Proceedings, 28(4), 517–520. Hoyle, F. C. (n.d.). Managing soil organic matter: A practical guide (GRDC Project Code KDI00023). Department of Agriculture and Food Western Australia. Hoyle, F. C., D’Angiolo, M., & Murphy, D. V. (2011). Soil organic carbon content and composition under contrasting grain cropping systems in a semi-arid environment. Soil & Tillage Research, 113(2), 104–109. Lacoste, M., Lawes, R., Ducourtieux, O., & Flower, K. (2016). Comparative agriculture methods capture distinct production practices across a broadacre Australian landscape. Agriculture, Ecosystems & Environment, 233, 381–395. McKenzie, N., Jacquier, D., Isbell, R., & Brown, K. (2004). Australian soils and landscapes: An illustrated compendium. CSIRO Publishing. Moore, G., Dolling, P., Porter, B., & Leonard, L. (1998). Soil acidity. In G. Moore (Ed.), Soilguide: A handbook for understanding and managing agricultural soils (Bulletin No. 4343). Agriculture Western Australia. Rayment, G. E., & Higginson, F. R. (1992). Australian laboratory handbook of soil and water chemical methods. Inkata Press. Rengasamy, P., & Churchman, G. J. (1999). Cation exchange capacity, exchangeable cations and sodicity. In K. I. Peverill, L. A. Sparrow, & D. J. Reuter (Eds.), Soil analysis: An interpretation manual. CSIRO Publishing. Roberts, R. P., & Shier, F. L. (1960). The development of Western Australian sand plain soils for agriculture. Journal of the Department of Agriculture, Western Australia, Series 4, 1(10), 855–864. Turpault, M. P., Nys, C., & Calmet, J. P. (2005). Impact of Douglas fir on an acid brown soil in the Morvan, France. Soil Use and Management, 21(1), 6–13. Williams, C. H., & Donald, C. M. (1957). Changes in organic matter and pH in a podzolic soil as influenced by subterranean clover and superphosphate. Australian Journal of Agricultural Research, 8(2), 179–189. Connect with Leonie Instagram: @agfromthegroundup Website: www.agriculturefromthegroundup.com.au