The two hosts really have great chemistry with each other; I'd honestly listen to them review cooking books from the 50's just to hear how well they play off each other and make clever references.
Behind the humour there's also some solid criticism. These guys are definitely on the negative side, the whole podcast is about picking apart systems and showing how they don't work or how the setting doesn't make sense, but it's still good to listen to them get salty, and they're more than willing to admit that they would play many of the games that they spent an hour debasing (they enjoy Rifts, for God's sake, they're not heartless). Definitely worth listening to, even to only to find out how bad some developers were in the 90's.